Beilstein J. Org. Chem.2020,16, 674–680, doi:10.3762/bjoc.16.65
University, Nablus, Palestine Merck KGaA, Liquid Crystal R&D Chemistry, Frankfurter Str. 250, 64293 Darmstadt, Germany 10.3762/bjoc.16.65 Abstract This paper describes the synthesis of a series of organicliquidcrystals (LCs) containing selectively fluorinated cyclopropanes at their termini. The syntheses
negative dielectric anisotropy. The study gives some guidance into effective structure–property relationships for the design of LCs containing selectively fluorinated cyclopropane motifs.
Keywords: dielectric anisotropy; difluorocarbene; organicliquidcrystals; selectively fluorinated cyclopropanes
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Graphical Abstract
Figure 1:
Examples of liquid crystal candidates with negative values for dielectric anisotropy (Δε) [6-10].